Emissive Cyanide-Bridged Bimetallic Compounds as Building Blocks for...
A series of cyanide-bridged bimetallic compounds of the general formula [Ru(L)(bpy)(µ-NC)(M)]2-/-/2+ (L = tpy, 2,2’-6’,2’’-terpyridine, or tpm, tris(1-pyrazolil)methane, bpy = 2,2’-bipyridine, M =...
View ArticleExtended Spectral Response in In0.82Ga0.18As/InP Photodetector using InP as a...
Extended spectral response InGaAs detectors have been grown, fabricated, and characterized for near-infrared detection. The atomic structure of the In0.82Ga0.18As/InP interface was investigated to...
View ArticleB-DNA Characteristics are Preserved in Double Stranded d(A)3[round bullet,...
We report the results of first comprehensive DFT study on the d(A)3•d(T)3 and d(G)3•d(C)3 nucleic acid duplexes. The ability of mini-helixes to preserve the conformation of B-DNA in the gas phase and...
View ArticleSyntheses of bis(pyrrolylaldiminato)aluminum complexes for the polymerisation...
Seven bis(pyrrolylaldiminato)aluminum methyl complexes were synthesized from the reactions of AlMe3 and two equiv. of the corresponding pyrrolylaldimine ligands. The ligands were modified to have...
View ArticleMechanism of Two-Dimensional Crystal Formation from Soft Microgel Particles
The mechanism of two-dimensional (2D) crystal formation from air-drying suspension of soft microgel particles is investigated via in situ confocal laser scanning microscopy (CLSM). According to the...
View ArticleAnthracene-bisphosphonate based novel fluorescent organic nanoparticles...
We report the first synthesis and use of a well defined fluorescent organic nanoparticle (FON), tetraethyl anthracene-9,10-diyl-9,10-bis(phosphonate) [TEABP], as a selective anticancer candidate by...
View ArticlePreparation of carbon nanomaterials from molecular precursors
The preparation of carbon nanomaterials has been the focus of many research groups over the last twenty years. Traditionally, the synthesis of these materials has been accomplished using physical...
View ArticleDensity dependence of the yield of hydrated electrons in the low-LET...
Monte Carlo simulations were used to calculate the yield of hydrated electrons (eaq−) in the low-linear energy transfer radiolysis of supercritical water at 400 °C as a function of water density over...
View ArticleOscillating fronts produced by spinodal decomposition of metastable ordered...
Mesophase-particle mixtures are emerging functional material systems whose structure, dynamics and formation through phase transitions is poorly understood. In this paper novel phase transitions in a...
View ArticleSelectivity enhancement in the aqueous acid-catalyzed conversion of glucose...
In this work we wish to show that choline chloride (ChCl), a cheap and safe quaternary ammonium salt industrially produced at thousand tons per year through a 100 % atom economy process, is capable of...
View ArticleSingle Amino Acid based Self-Assembled Structure
Single amino acids, Phenylalanine, Tyrosine and Glycine, have been evaluated for fibrillar structure under neutral, aqueous conditions using scanning electron microscopy, transmission electron...
View ArticleSignificantly Improved High-Rate Li-Ion Batteries Anode by Encapsulating Tin...
Novel nanostructures, e. g. core-shell or yolk-shell, sword-sheath, coaxial nanotubes, etc., are extensively explored for their potential application in modifying electrodes durability in lithium ion...
View ArticleTemperature-dependent enhancement of oxygen reduction reaction activity for...
Interconnected carbon shells with a high nitrogen-doped level were successfully synthesized by a green self-assembly route. The synthesized carbon shells exhibited considerably enhanced oxygen...
View ArticleImportance of co-donor field strength in the preparation of tetradentate...
Although bis(α-diimine)Ni complexes were prepared when amine-substituted chelates were added to Ni(COD)2, the incorporation of strong-field phosphine donors allowed the isolation of (κ4-N,N,P,P-DI)Ni...
View ArticleHydrogen-fluorine exchange in NaBH4-NaBF4
Hydrogen-fluorine exchange in the NaBH4NaBF4 system is investigated with a range of experimental methods combined with DFT calculations and a possible mechanism for the reactions is proposed....
View ArticleSynthesis and electrocatalytic properties of tetrahexahedral, polyhedral, and...
Tetrahexahedral, polyhedral, and branched Pd@Au core–shell nanostructures were selectively produced by manipulating their growth thermodynamics and kinetics. The current density in the electrochemical...
View ArticleMonosubstituted alkenyl amino acids for peptide “stapling”
Alkenylglycine amino acids were assessed as potential candidates for hydrocarbon stapling and shown to be effective in stapling of the BID BH3 peptide....
View ArticleTheoretical study on low-lying states of Ga2X(X= P, As) with coupled-cluster...
Low-lying states of Ga2P and Ga2As are investigated with the equation-of-motion coupled-cluster approach for ionized states at the singles and doubles level (EOMIP-CCSD) together with CCSD, CCSD(T),...
View ArticleVisualizing physical, electronic, and optical properties of organic...
The most interesting active layer system for organic photovoltaic cells is the bulk heterojunction (BHJ). The general structure of a BHJ is a network of domains, which contain blended donor and...
View ArticleLow-temperature, solution-processed, layered V2O5 hydrate as the...
Layered V2O5 hydrate has been applied as the hole transport layer (HTL) in organic solar cells (OSCs). V2O5 is obtained from a sodium metavanadate solution in water under ambient conditions, resulting...
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