Coordination environment evolution of Eu3+ during the dehydration and...
There are limited photoluminescence (PL) studies for rare earth borates with crystalline water molecules, which were usually supposed to have low PL efficiency because the vibrations of H2O or -OH may...
View ArticleHigh-Throughput Metabolic Genotoxicity Screening with a Fluidic Microwell...
A high throughput electrochemiluminescent (ECL) chip was fabricated and integrated into a fluidic system for screening toxicity-related chemistry of drug and pollutant metabolites. The chip base is...
View ArticleThe Evalution of NIR-Absorbing Porphyrin Derivatives as Contrast Agents in...
Six free base tetrapyrrolic chromophores, three quinoline-annulated porphyrins and three morpholino¬bacteriochlorins, that absorb light in the near-IR range and possess, in comparsion to regular...
View ArticleNovel Pharmaceutical Compositions through Co-crystallization of Racetams and...
Grinding of solid brivaracetam (BRV) and seletracetam (SEL) with inorganic lithium salts yields original metal ionic co-crystals (ICCs) characterized by markedly different thermal properties with...
View ArticleCO2/N2 Separations with Mixed-Matrix Membranes Containing Mg2(dobdc)...
Nanocrystals of M2(dobdc) (M = Mg, Ni, Zn; dobdc4– = 1,4-dioxido-2,5-benzenedicarboxylate), also known as M-MOF-74 or CPO-27-M, with diameters of ~100 nm or less were synthesized using a...
View ArticleStructural motif-dependent magnetic diversity observed in three-dimensional...
Three extended three-dimensional (3D) magnetic metal-organic frameworks (MMOFs), {[Mn3(H2O)2(atz)4Cl2]•2CH3OH}n (1), {[Mn2(H2O)(atz)2(ip)]•C2H5OH}n (2), and {[Mn2(H2O)2(atz)(btc)]•3H2O•0.7CH3OH}n (3)...
View ArticleA Nanocomposite of Copper (II) Functionalized Graphene and Application for...
Reduced graphene oxide is modified with sulfanilic acid diazonium salt followed by copper (II) chelating to form a Cu complex nanocomposite. Characterizations by using Raman Spectroscopy, FTIR and...
View ArticleThe reactivity of molybdenum pentachloride with ethers: routes to the...
The reactivity of molybdenum pentachloride, 1, with a selection of mono- and diethers was investigated at room temperature in a non-coordinating solvent (dichloromethane). The Mo(iv) complex...
View ArticleA Au-functionalized ZnO nanowire gas sensor for detection of benzene and toluene
A novel sensing hybrid-material of Au nanoparticles (Au NPs)-functionalized ZnO nanowires (Au–ZnO NWs) was successfully synthesized by a two-stage solution process. First, ZnO NWs were fabricated via...
View ArticleThe semiochemistry of aphids
Covering: up to the end of 2012Chemical signalling between aphids (small insects that suck plant sap) for mating and avoidance of antagonistic organisms, and between aphids and plants for location of...
View ArticleEpinephrine electro-oxidation highlights fast electrochemistry at the...
Macroscale and nanoscale measurements of epinephrine electro-oxidation at graphite electrodes, with different step edge densities, demonstrate unequivocally that the reaction occurs readily at the...
View ArticleTheory of Two-dimensional Self-Assembly of Janus Colloids: Crystallization...
We study the rich crystalline phase behavior of amphiphilic spherical Janus colloids using a new formulation of self-consistent phonon theory that includes coupled translational and rotational...
View ArticleIn situ ATR-IR observation of nucleation and crystal growth of KH2PO4 in...
In situ Attenuated Total Reflectance-Infrared (ATR-IR) spectroscopy was used to record and characterize the crystallization of KH2PO4 (KDP) from aqueous solution with pH = 1.01-6.96. In the...
View ArticleThe competition between halogen bonds and C-H hydrogen bonds: the structure...
A combination of single-crystal X-ray (at 110 and 200 K) and high-resolution neutron powder diffraction (110 K only) using perdeuterated samples has been used to re-determine the crystal structure of...
View ArticleThiadiazole-functional porous metal-organic framework as the luminescent...
The solvothermal reaction of 4,4’-(benzothiadiazole-4,7-diyl)dibenzoate and Zn(II) leads to the generation of a interdigitating three-dimensional (2D+2D→3D) porous metal-organic framework, which...
View ArticleTuning nanopore surface polarity and rectification properties through...
Enzyme-catalyzed reactions inside nanoconfined geometries promote sensitive changes in the surface charge polarity and the concomitant permselective transport properties of the single conical...
View ArticleSelective One-Pot Syntheses of PtII-CuI Heterobimetallic Complexes of...
We report both the stepwise and one-pot syntheses of PtII-CuI hetero-dinuclear complexes using 4,5-diazafluorenide (L-) and 9-(2-(diphenylphosphino)ethyl)-4,5-diazafluorenide (Lp-) as binucleating...
View ArticleDinuclear lanthanide complexes bridged by nitronyl nitroxide radical ligands...
Three novel binuclear lanthanide–radical complexes [Ln2(acac)4(NITPhO)2] (Ln(iii) = Gd 1, Eu 2, Dy 3; acac = acetylacetonato and NITPhOH =...
View ArticleOptimal control of molecular fragmentation with homologous families of...
This work investigates laser optimally controlled fragmentation in a series of chemically related halomethane compounds in order to determine the extent to which regular trends in objective yields are...
View Article6-Oxopyriphlorins
Reaction of 2,6-pyridinedicarbaldehyde with a series of tripyrranes in the presence of trifluoroacetic acid, followed by oxidation of a pyriphlorin intermediate with silver(i) acetate, gave...
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