Palladium Catalyzed N-H Bond Insertion and Intramolecular Cyclization...
The palladium catalyzed carbenoid based N-H insertion and electronic effect controlled 5-exo-trig or 6-endo-trig mode Heck cyclization in one-pot has been realized for ortho-iodoanilines, in which...
View Article68Ga Chelating Bioorthogonal Tetrazine Polymers for the Multistep labeling of...
We have developed a 68Ga metal chelating bioorthogonal tetrazine dextran probe that is highly reactive with trans-cyclooctene modified monoclonal antibodies for multistep imaging applications....
View ArticleAg2S–AgInS2: p–n junction heteronanostructures with quasi type-II band alignment
We report here the fabrication of a p–n junction diode in a single nanostructure by synthesizing a heterostructure involving n-type AgInS2 and p-type Ag2S. The quasi type-II band alignment between...
View ArticleWith the same Clar formulas, do the two-dimensional sandwich nanostructures...
The “perturbation” effects (i.e. hyperconjugation, electronegativity, and conjugation) on the structural, electronic, and magnetic properties of three kinds of two-dimensional (2D) X–Cr–X (X = C4H,...
View ArticleIron-Catalyzed Carbonylative Suzuki Reactions under Atmospheric Pressure of...
The first highly effective iron-catalyzed carbonylative Suzuki reaction has been developed. Substrates with electron-donating or electron-withdrawing functionality, ortho-substitution, as well as...
View ArticleElectrochemical Sensing of Hepatocyte Viability
We investigated the use of amperometric and chronoamperometric methods with a double mediator system and screen-printed electrodes (SPEs) for the electrochemical sensing of hepatocyte viability. Cell...
View ArticleOrientation dependence of electrical properties of large-sized sodium...
Lead-free (K0.25Na0.75)NbO3 (KNN25/75) single crystals with dimensions of Ø30 × 10 mm were successfully grown by a top seeded solution growth technique (TSSG). The X-ray diffraction pattern shows that...
View ArticleGeochemical evolution of groundwater salinity at basin scale: A case study...
A hydrogeochemical investigation using integrated methods of stable isotopes (18O, 2H), 87Sr/86Sr ratios, Cl/Br ratios, chloride-mass balance, mass balance and hydrogeochemical modeling was conducted...
View ArticleOne-step fabrication of a highly conductive and durable copper paste and its...
A highly conductive and durable copper (Cu) paste was successfully fabricated via acid treatment and mechanical blending with corrosion inhibitors. A screen-printed Cu pattern was evaluated as a...
View ArticleThe electrochemical self-assembly of hierarchical dendritic Bi2Se3...
Bismuth selenide (Bi2Se3) has proven to be an important material in thermoelectric and topological insulator applications. We report here a simple electrochemical self-assembly route for the...
View ArticleConceptual DFT: chemistry from the linear response function
Within the context of reactivity descriptors known in conceptual DFT, the linear response function (χ(r,r′)) remained nearly unexploited. Although well known, in its time dependent form, in the solid...
View ArticleSelective synthesis of secondary amines from nitriles using Pt nanowires as a...
A new one-pot method has been developed for the selective synthesis of secondary amines via reductive amination of the corresponding nitriles using Pt nanowires as a catalyst. This method allows for...
View ArticleFluorescent detection of RDX within DHPA-containing metal–organic polyhedra
By incorporating the dihydropyridine amido (DHPA) group into the rationally designed ligand systems, metal–organic molecular polyhedra were obtained via self-assembly for the luminescent sensing of...
View ArticleCopolymerization of cyclohexene oxide with CO2 catalyzed by tridentate...
A new class of complexes based on titanium(iv) bearing a bisanionic mer-tridentate N-heterocyclic carbene ligand were investigated for the copolymerization of cyclohexene oxide with CO2. Upon addition...
View ArticleNovel organic–inorganic hybrid soft xerogels with lanthanide complexes...
This paper provides the strategy to prepare luminescent sandwich structured hybrid materials [Ln(L)4]-IM+-Al/Ti (Ln = Eu, Sm; L = 2-thenoyltrifluoroacetonate (TTA); Ln = Tb, L = trifluoroacetylacetonate...
View ArticleDynamics of metal uptake by charged soft biointerphases: impacts of...
A comprehensive theory is elaborated for the dynamics of metal ion uptake by charged spherical microorganisms. The formalism integrates the interplay over time between bulk metal depletion, metal...
View ArticleComputational and experimental study of O-glycosylation. Catalysis by human...
It is estimated that...
View Article‘Janus-type’ organopotassium chemistry observed in deprotonation of mesoionic...
The first direct observation of the tautomeric equilibrium between mesoionic imidazolium aminides (IA) and amino NHCs (AC) shows its dependence on the aminide substituent. A potassium...
View ArticleRecent developments in the application of nanomaterials to understanding...
This perspective offers an overview of using nanomaterials for understanding cobalt catalysed Fischer–Tropsch chemistry. Nanomaterials now afford unprecedented control of size, shape and structure at...
View ArticleHuman Serum Albumin Binding to Silica nanoparticles - effect of protein fatty...
Fatted (F-HSA) and defatted (DF-HSA) versions of human serum albumin behave differently in their interaction with silica nanoparticles premixed in buffer solutions. In both cases a silica containing...
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