A Novel Microfluidic Chip Electrophoresis Strategy for Simultaneous...
A new sense of high throughput and parallel optical sensoring platform with single color probe based on microfluidic chip electrophoresis combined with aptamer-carboxyfluorescein/graphene oxide energy...
View ArticleBorohydrides: From Sheet to Framework Topologies
The five novel compounds ALiM(BH4)4 (A = K or Rb; M = Mg or Mn) and K3Li2Mg2(BH4)9 crystallizing in the space groups Aba2 and P2/c, respectively, represent the first two-dimensional topologies amongst...
View ArticleBase-Promoted Aryl-Bromine Bond Cleavage with Cobalt(II) Porphyrins via...
Aryl-bromine bonds are successfully cleaved by cobalt(II) porphyrins in basic media to give Co(por)Ar (por = porphyrin) in good yields. Mechanistic studies suggested that the aryl-bromine bond is...
View ArticleAnisotropic terahertz dielectric responses of sodium nitrate crystals
Terahertz (THz) spectroscopy has become an effective tool to characterize the low-frequency rotational and vibrational modes of molecules. In addition, novel THz dielectric responses and optical...
View ArticleEnhancement of Intensity in Microwave-Assisted Laser-Induced Breakdown...
An enhancement of emission intensity from laser ablation plume, obtained by coupling a pulsed microwave using a simple wire antenna, is demonstrated to compensate the sensitivity reduction of higher...
View ArticleSynthesis and characterisation of a novel Europium(III)-containing...
A novel luminescent metal-containing POSS, bearing in the structure the europium ion, was synthesized and characterized. The corner-capping reaction between the partially condensed isobutyl-POSS...
View ArticleSelective Oxidation of Cyclohexene to Adipic Acid over Silver supported...
We have developed a new synthesis strategy to prepare ~5 nm metallic silver nanoparticles (AgNPs) supported on tungsten oxide (WO3) nanorod with diameter between 40-60 nm, in presence of cationic...
View ArticleChoosing dyes for cw-STED nanoscopy using self-assembled nanorulers
Superresolution microscopy is currently revolutionizing optical imaging. A key factor for getting images of highest quality is – besides a well-performing imaging system – the labeling of the sample....
View ArticleSpatially marking and quantitatively counting membrane immunoglobulin M in...
A probe composed of an aptamer and a silver cluster, where the aptamer targets mIgM of live cells and the silver cluster provides fluorescent imaging and mass quantification of mIgM of live cells, is...
View ArticleCotton Fabric-based Electrochemical Device for Lactate Measurement in Saliva
Lactate measurement is vital in clinical diagnostics especially among trauma and sepsis patients. Recent years have shown saliva samples to be an excellent applicable alternative for non-invasive...
View ArticleSynthesis of silk-based microcapsules by desolvation and hybridization
Single-component porous silk microcapsules were synthesized by one-step desolvation method using PLGA spheres as sacrificial templates. Subsequently, AuNRs-T5 were utilized to synthesize silk-based...
View ArticleUV-mediated tuning of surface biorepulsivity in aqueous environment
While it is well-known that oligoethylene glycol (OEG) terminated self-assembled monolayers (SAMs) can be deteriorated by UV irradiation in air, we now report that the analogous modification can also...
View ArticlePreparation of Conjugated 1,3-Enynes using Rh(III) Catalysed Alkynylation of...
An experimentally simple additive free Rh (III) catalysed direct alkynylation of alkenes has been developed. This protocol employs commercially available TIPS-EBX as the alkyne source, giving access...
View ArticlepH dependent facile synthesis of di- and tri-nuclear oxime based Cu(II)...
Oxime based tridentate Schiff base ligand 3-[3-(dimethylamino)propylimino]butan-2-one oxime (HL) produced two dinuclear compounds [Cu2L2(H2O)](ClO4)2 (1) and [Cu2L2(H2O)](BF4)2 (2), and a hexanuclear...
View ArticleRevised crystal structure and luminescent properties of gadolinium...
The structure of gadolinium oxyfluoride nanoparticles was revised. Extensive studies including X-ray diffraction and Rietveld refinement as well as Fourier transform infrared spectroscopy and Raman...
View ArticleMass Spectrometric Investigation of the Role of the Linking Polypeptide Chain...
DNA polymerase I offers great promise for a wide range of biotechnological applications due to its capability to add labeled nucleotides into double-stranded large DNA molecules by using both...
View ArticleEnergy-Resolved Collision-Induced Dissociation Pathways of Model N-Linked...
Tandem mass spectrometry (MS/MS) of glycopeptides stands among the principal analytical approaches for assessing protein glycosylation in a site-specific manner. The aims of such experiments are often...
View ArticleGroup 4 Metal Complexes with New Chiral Pincer NHC-Ligands: Synthesis,...
Chiral group 4 NHC-metal complexes were prepared in good yields by amine elimination from M(NR2)4 (M = Ti, Zr, Hf; R = Me, Et) and chiral pincer NHC-ligands, 4 (4a and 4b), 5 and 6, that are derived...
View ArticleMacrocyclic arylopeptoids – a novel type of cyclic N-alkylated aromatic...
The head-to-tail conversion of linear arylopeptoids (oligomeric N-substituted aminomethyl benzamides) into the derived novel macrocycles has enabled the first X-ray structures of arylopeptoid...
View ArticleEnhancement of Thermal Stability in Bismuth Phosphate by Ln3+ Doping for...
Bismuth phosphate represents one promising class of luminescent host materials, while its applications are challenged by structural instability. In this work, series of nanocrystals Bi1-xLnxPO4 (x =...
View Article
