A Down-Scaled Fluorimetric Determination of the Solubility Properties of...
A miniaturized fluorescence assay on multi-well plates has been developed to study the solubility enhancement effect of (2-hydroxypropyl)-β-cyclodextrin on three anti-tumor alkaloids. The measurement...
View ArticleSynthesis of Heterocyclic-Fused Benzofurans via C–H Functionalization of...
An efficient method to effect C–O cyclization was developed via the C–H functionalization of chromones and coumarins, affording heterocyclic-fused benzofurans....
View ArticleANALOGY AMONG MICROFLUIDICS, MICROMECHANICS, AND MICROELECTRONICS
We wish to illuminate the analogous link between microfluidic-based devices, and the already established pairing of micromechanics and microelectronics to create a triangular/three-way scientific...
View ArticleTotal Synthesis of Eryvarin H and its Derivatives and their Biological...
Total synthesis of Eryvarin H and the biological investigation of its analogues as a potential inverse agonist of ERRγ are depicted here. Among 13 analogues prepared by modular synthetic route,...
View ArticlePolymer-grafted nanoparticles prepared by surface-initiated polymerization:...
The polymer-grafted nanoparticles prepared by the surface-initiated polymerization induced from the spherical surface is studied by the coarse-grained molecular dynamics simulations combined with the...
View ArticleMono- and di-nuclear photoluminescent complexes of zinc(II), cadmium(II) and...
Reaction of α-pyridoin and N-phenyl-o-phenylenediamine affords 2-(2-(phenylamino)phenylimino)-1,2-di(pyridin-2-yl)ethanol (L) which undergoes cyclization to a chiral diimine,...
View ArticleOxidation-state dependent electrocatalytic activity of iridium nanoparticles...
Nanocomposites of iridium nanoparticles (Ir NPs), supported on graphene nanosheets, are synthesized and their electrocatalytic acitivities in the oxygen reduction reaction (ORR) are studied depending...
View ArticleHalogen bonding in fluorine: experimental charge density study on...
The enigmatic type II C–F [] F–C and C–F [] S–C interactions in pentafluorophenyl 2,2′-bithiazole are shown to be realistic “σ-hole” interactions based on high resolution X-ray charge density...
View ArticleThe force of transporting single amino-acid into the living cell measured by...
We used single molecule force spectroscopy (SMFS) to investigate the interactions between single cysteine and the amino acid transporter in eukaryotic cell membranes. From the AFM force spectroscopy,...
View ArticleStereoselective Synthesis of Arabidopsis CLAVATA3 (CLV3) glycopeptide, unique...
The unique hydroxylproline (Hyp)-linked O-glycan modification has been found as the common process in the hydroxyproline-rich glycoproteins (HRGPs). The modification occurs through post-translational...
View ArticleComputer simulations of ionic liquids at electrochemical interfaces
Ionic liquids are widely used as electrolytes in electrochemical devices. In this context, many experimental and theoretical approaches have been recently developed for characterizing their interface...
View ArticleOxidation of 2-arylindoles for synthesis of 2-arylbenzoxazinones with oxone...
A novel and efficient method for the oxidation of 2-arylindoles to synthesize 2-arylbenzoxazinones which utilizing oxone as the sole oxidant has been developed. The reaction tolerates a wide range of...
View ArticleLewis-base-promoted copper-based catalyst for highly efficient hydrogenation...
The gas-phase hydrogenation of dimethyl 1,4-cyclohexane dicarboxylate to 1,4-cyclohexane dimethanol was performed on a well-dispersed Cr-free supported copper-based catalyst derived from Cu-Mg-Al...
View ArticleDiscrete spherical hexadecavanadates incorporating a bromide with oxidative...
Two discrete hexadecavanadates, (n-Bu4N)4[V16O38(X)] (X = Cl− (1) and X = Br− (2)), were synthesized by a reaction of [V10O26]4− with a template anion resulting in the incorporation of chloride or...
View ArticleAncillary ligand-assisted structural diversity of six new metal-organic...
Solvothermal reactions of tricarboxylate ligand 5-(4-carboxybenzoylamino)-isophthalic acid (H3L), dipyridyl linkers (bpe, bpa and bpy) and divalent metal ions (Co2+, Cd2+, Zn2+ and Ni2+) provided a...
View ArticleA molecular ‘traffic light’: highly selective cyanide sensing in aqueous...
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance....
View ArticleFabrication of Artifical Toroid Nanostructures by Modified [small beta]-sheet...
Facial peptide P1 carrying repeating hydrophobicand hydrophilic residues as well as lysine terminals self-assemble into uniform toroid structures. The sensitive balance between the hydrophobic...
View Article1D, 2D and 3D Coordination polymers of 5,5'-methylenebis(oxy)dinicotinic acid...
A series of new coordination polymers of the 5,5'-methylenebis(oxy)dinicotinic acid ligand with various metal ions, have been synthesized under hydro(solvo)thermal conditions and characterized by...
View ArticleChemistry and formulations for siRNA therapeutics
Small interfering ribonucleic acids (siRNAs) form potentially the most important class of next generation therapeutics. However, achieving their efficient delivery in the correct dose, time and...
View ArticleSix new 3d-4f heterometallic coordination polymers constructed from...
Reactions of lanthanide chlorides, copper hydroxycarbonate and 3,5-pyrazole dicarboxylic acid (H3pdc) under hydrothermal conditions result in six new 3d-4f heterometallic coordination polymers with...
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